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Tectonic plate convergence is accommodated across the continental lithosphere via discrete lithospheric subduction or distributed shortening and thickening. These end-member deformation modes control intra-plate mountain building, but their selection mechanism remains unclear. The variable composition of the continental crust and lithospheric mantle, which impacts its density and rheology, can be inferred by the distribution of magnetic-indicated crustal iron. Here we demonstrate that vertically coherent pure-shear shortening dominated the active Tian Shan orogen, central Asia, based on high-resolution aeromagnetic imaging and geophysical-geodetic observations. Integrating these findings with thermomechanical collisional models reveals that the mode of intracontinental deformation depends on contrasts in lower crust composition and mantle lithosphere depletion between the converging continents and central orogenic region. Distributed shortening prevails when the converging continents have a more iron-enriched mafic crust and iron-depleted mantle lithosphere when compared to the intervening orogenic region. Conversely, continental subduction occurs without such lithospheric contrasts. This result explains how the Tian Shan orogen formed via distributed lithospheric thickening without continental subduction or underthrusting. Our interpretations imply that iron distribution in the crust correlates with lithospheric compositional, density, and rheological structure, which impacts the preservation and destruction of Earth’s continents, including long-lived cratons, during intracontinental orogeny. 

Cooperative perception that integrates sensing capabilities from both infrastructure and vehicle perception sensors can greatly benefit the transportation system with respect to safety and data acquisition. In this study, we conduct a preliminary evaluation of such a system by integrating a portable lidar-based infrastructure detection system (namely, Traffic Scanner [TScan]) with a Society of Automotive Engineers (SAE) Level 4 connected and automated vehicle (CAV). Vehicle-to-everything (V2X) communication devices are installed on both the TScan and the CAV to enable real-time message transmission of detection results in the form of SAE J2735 basic safety messages. We validate the concept using a case study, which aims at improving CAV situation awareness and protecting vulnerable road user (VRU) safety. Field testing results demonstrate the safety benefits of cooperative perception from infrastructure sensors in detecting occluded VRUs and helping CAVs to plan safer (i.e., higher post-encroachment time) and smoother (i.e., lower deceleration rates) trajectories. 

The consumption of synthetic polymers has ballooned; so has the amount of post-consumer waste generated. The current polymer economy, however, is largely linear with most of the post-consumer waste being either landfilled or incinerated. The lack of recycling, together with the sizable carbon footprint of the polymer industry, has led to major negative environmental impacts. Over the past few years, chemical recycling technologies have gained significant traction as a possible technological route to tackle these challenges. In this regard, olefin metathesis, with its versatility and ease of operation, has emerged as an attractive tool. Here, we discuss the developments in olefin-metathesis-based chemical recycling technologies, including the development of new materials and the application of olefin metathesis to the recycling of commercial materials. We delve into structure–reactivity relationships in the context of polymerization–depolymerization behavior, how experimental conditions influence deconstruction outcomes, and the reaction pathways underlying these approaches. We also look at the current hurdles in adopting these technologies and relevant future directions for the field. 

Connected and automated vehicles (CAVs) provide various valuable and advanced services to manufacturers, owners, mobility service providers, and transportation authorities. As a result, a large number of CAV applications have been proposed to improve the safety, mobility, and sustainability of the transportation system. With the increasing connectivity and automation, cybersecurity of the connected and automated transportation system (CATS) has raised attention to the transportation community in recent years. Vulnerabilities in CAVs can lead to breakdowns in the transportation system and compromise safety (e.g., causing crashes), performance (e.g., increasing congestion and reducing capacity), and fairness (e.g., vehicles fooling traffic signals). This paper presents our perspective on CATS cybersecurity via surveying recent pertinent studies focusing on the transportation system level, ranging from individual and multiple vehicles to the traffic network (including infrastructure). It also highlights threat analysis and risk assessment (TARA) tools and evaluation platforms, particularly for analyzing the CATS cybersecurity problem. Finally, this paper will provide valuable insights into developing secure CAV applications and investigating remaining open cybersecurity challenges that must be addressed. 

Abstract The factors that control strain partitioning along plate boundaries and within continental interiors remains poorly resolved. Plate convergence may be accommodated via distributed crustal shortening or discrete crustal‐scale strike‐slip faulting, but what controls these differing modes of deformation is debated. Here we address this question by examining the actively deforming regions that surround the Tarim Basin in central Asia, where deformation is uniquely partitioned into predominately strike‐slip faults in the east and distributed fold‐thrust belts in the west to accommodate Cenozoic India‐Asia plate convergence. We present integrated geological and geophysical observations to elucidate patterns in crustal deformation and compositional structure in and around the Tarim Basin. The thrust‐dominated western Tarim Basin correlates with a strongly‐magnetic lower crust, whereas strike‐slip faulting along the eastern margins of the Tarim Basin lack such magnetic signals. We suggest that the lower crust of the western Tarim is more mafic and stronger than in the east, which impacts intra‐plate strain partitioning. A stronger lower crust results in vertical decoupling to drive mid‐crust horizontal detachments and facilitate thrust faulting, whereas a more homogenized crust favored vertical transcrustal strike‐slip faulting. These rheological differences likely originated from the impingement of the Permian Tarim plume focused in the west. A comparison with the Longmen Shan of eastern Tibetan Plateau reveals remarkably similar strain partitioning that correlates with variations in foreland rheology. Our results highlight how variations in lower‐crust viscosity impact strain partitioning in an intra‐plate setting and how plume processes exert a strong control on later continental tectonic processes. 

Deformation-resistant cratons comprise >60% of the continental landmass on Earth. Because they were formed mostly in the Archean to Mesoproterozoic, it remains unclear if cratonization was a process unique to early Earth. We address this question by presenting an integrated geological-geophysical data set from the Tarim region of central Asia. This data set shows that the Tarim region was a deformable domain from the Proterozoic to early Paleozoic, but deformation ceased after the emplacement of a Permian plume despite the fact that deformation continued to the north and south due to the closure of the Paleo-Asian and Tethyan Oceans. We interpret this spatiotemporal correlation to indicate plume-driven welding of the earlier deformable continents and the formation of Tarim’s stable cratonic lithosphere. Our work highlights the Phanerozoic plume-driven cratonization process and implies that mantle plumes may have significantly contributed to the development of cratons on early Earth. 

Fluorinated polymers are important functional materials for a broad range of applications, but the recycling of current fluorinated polymers is challenging. We present the first example of semi-fluorinated polymers that can undergo chemical recycling to form the corresponding monomers under ambient conditions. Prepared through ring-opening metathesis polymerization of functionalized trans -cyclobutane fused cyclooctene ( t CBCO) monomers, these polymers show tunable glass transition temperatures (−2 °C to 88 °C), excellent thermal stability (decomposition onset temperatures >280 °C) and hydrophobicity (water contact angles >90°). The hydrophobicity of the semi-fluorinated polymers was further utilized in an amphiphilic diblock copolymer, which forms self-assembled micelles with a size of ∼88 nm in an aqueous solution. Finally, through an efficient, regioselective para -fluoro-thiol substitution reaction, post-polymerization functionalization of a polymer with a pentafluorophenyl imide substituent was achieved. The ease of preparation, functionalization, and recycling, along with the diverse thermomechanical properties and demonstrated hydrophobicity make the t CBCO-based depolymerizable semi-fluorinated polymers promising candidates for sustainable functional materials that can offer a solution to a circular economy.